Publications associated with Oxide Electronics

Revealing the nature of photoluminescence emission in the metal-halide double perovskite Cs2AgBiBr6

Journal of Materials Chemistry C Royal Society of Chemistry 7 (2019) 8350-8356

SJ Zelewski, JM Urban, A Surrente, DK Maude, A Kuc, L Schade, R Johnson, M Dollmann, P Nayak, H Snaith, P Radaelli, R Kudrawiec, R Nicholas, P Plochocka, M Baranowski

<p>Double perovskite crystals such as Cs<small><sub>2</sub></small>AgBiBr<small><sub>6</sub></small> are expected to overcome the limitation of classic hybrid organic–inorganic perovskite crystals related to the presence of lead and the lack of structural stability. Perovskites are ionic crystals in which the carriers are expected to strongly couple to lattice vibrations. In this work we demonstrate that the photoluminescence (PL) emission in Cs<small><sub>2</sub></small>AgBiBr<small><sub>6</sub></small> is strongly influenced by the strong electron–phonon coupling. Combining photoluminescence excitation (PLE) and Raman spectroscopy we show that the PL emission is related to a color center rather than a band-to-band transition. The broadening and the Stokes shift of the PL emission from Cs<small><sub>2</sub></small>AgBiBr<small><sub>6</sub></small> is well explained using a Franck–Condon model with a Huang–Rhys factor of <em>S</em> = 11.7 indicating a strong electron–phonon interaction in this material.</p>

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