Dynamics of Counterion Condensation
ArXiv cond-mat/9905251 (1999)
Abstract:
Using a generalization of the Poisson-Boltzmann equation, dynamics of counterion condensation is studied. For a single charged plate in the presence of counterions, it is shown that the approach to equilibrium is diffusive. In the far from equilibrium case of a moving charged plate, a dynamical counterion condensation transition occurs at a critical velocity. The complex dynamic behavior of the counterion cloud is shown to lead to a novel nonlinear force-velocity relation for the moving plate.Collapse of Stiff Polyelectrolytes due to Counterion Fluctuations
ArXiv cond-mat/9901293 (1999)
Abstract:
The effective elasticity of highly charged stiff polyelectrolytes is studied in the presence of counterions, with and without added salt. The rigid polymer conformations may become unstable due to an effective attraction induced by counterion density fluctuations. Instabilities at the longest, or intermediate length scales may signal collapse to globule, or necklace states, respectively. In the presence of added-salt, a generalized electrostatic persistence length is obtained, which has a nontrivial dependence on the Debye screening length.Comment on ``Adsorption of Polyelectrolyte onto a Colloid of Opposite Charge''
ArXiv cond-mat/9901152 (1999)
Abstract:
In a recent Letter, Gurovitch and Sens studied the adsorption of a weakly charged polyelectrolyte chain onto an oppositely charged colloidal particle. By using a variational technique they found that the colloidal particle can adsorb a polymer of higher charge than its own, and thus be ``overcharged.'' I argue that the observed overcharging by a factor of 16/5 is indeed an artifact of the approximations involved in the study. Moreover, I show that the existence of overcharging depends crucially on the choice of the trial wave function, contrary to their claim.Motion-Induced Radiation from a Dynamically Deforming Mirror
ArXiv quant-ph/9803070 (1998)
Abstract:
A path integral formulation is developed to study the spectrum of radiation from a perfectly reflecting (conducting) surface. It allows us to study arbitrary deformations in space and time. The spectrum is calculated to second order in the height function. For a harmonic traveling wave on the surface, we find many different regimes in which the radiation is restricted to certain directions. It is shown that high frequency photons are emitted in a beam with relatively low angular dispersion whose direction can be controlled by the mechanical deformations of the plate.Path Integral Approach to the Dynamic Casimir Effect with Fluctuating Boundaries
ArXiv quant-ph/9802017 (1998)