Publications associated with Quantum Matter in High Magnetic Fields


Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system.

Chemical communications (Cambridge, England) 52 (2016) 12653-12656

JL Manson, JA Schlueter, KE Garrett, PA Goddard, T Lancaster, JS Möller, SJ Blundell, AJ Steele, I Franke, FL Pratt, J Singleton, J Bendix, SH Lapidus, M Uhlarz, O Ayala-Valenzuela, RD McDonald, M Gurak, C Baines

The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.


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