Publications


Topological insulators: Engineered heterostructures.

Nature materials 16 (2016) 3-4

T Hesjedal, Y Chen


Coupled commensurate charge density wave and lattice distortion in Na(2)Ti(2)Pn(2)O (Pn = As,Sb) determined by x-ray diffraction and angle-resolved photoemission spectroscopy

PHYSICAL REVIEW B 94 (2016) ARTN 104515

NR Davies, RD Johnson, AJ Princep, LA Gannon, J-Z Ma, T Qian, P Richard, H Li, M Shi, H Nowell, PJ Baker, YG Shi, H Ding, J Luo, YF Guo, AT Boothroyd


Spin resonance in the superconducting state of Li1-xFexODFe1-ySe observed by neutron spectroscopy

PHYSICAL REVIEW B 94 (2016) ARTN 144503

NR Davies, MC Rahn, HC Walker, RA Ewings, DN Woodruff, SJ Clarke, AT Boothroyd


Atomic-level structural and chemical analysis of Cr-doped Bi2Se3 thin films.

Scientific reports 6 (2016) 26549-

A Ghasemi, D Kepaptsoglou, LJ Collins-McIntyre, Q Ramasse, T Hesjedal, VK Lazarov

We present a study of the structure and chemical composition of the Cr-doped 3D topological insulator Bi2Se3. Single-crystalline thin films were grown by molecular beam epitaxy on Al2O3 (0001), and their structural and chemical properties determined on an atomic level by aberration-corrected scanning transmission electron microscopy and electron energy loss spectroscopy. A regular quintuple layer stacking of the Bi2Se3 film is found, with the exception of the first several atomic layers in the initial growth. The spectroscopy data gives direct evidence that Cr is preferentially substituting for Bi in the Bi2Se3 host. We also show that Cr has a tendency to segregate at internal grain boundaries of the Bi2Se3 film.


High Resolution STEM Study of Dy-doped Bi 2 Te 3 Thin Films

Microscopy and Microanalysis 22 (2016) 1516-1517

V Srot, P Schönherr, B Bussmann, SE Harrison, PA van Aken, T Hesjedal


Magnetic properties of and : Magnetic hysteresis with coercive fields of up to 55 T

Physical Review B 94 (2016)

J Singleton, JW Kim, CV Topping, A Hansen, E-D Mun, S Chikara, I Lakis, S Ghannadzadeh, P Goddard, X Luo, YS Oh, S-W Cheong, VS Zapf


Resonant elastic x-ray scattering from the skyrmion lattice in Cu2OSeO3

PHYSICAL REVIEW B 93 (2016) ARTN 214420

SL Zhang, A Bauer, H Berger, C Pfleiderer, G van der Laan, T Hesjedal


Robustness of superconductivity to competing magnetic phases in tetragonal FeS

PHYSICAL REVIEW B 94 (2016) ARTN 134509

FKK Kirschner, F Lang, CV Topping, PJ Baker, FL Pratt, SE Wright, DN Woodruff, SJ Clarke, SJ Blundell


Quantum Interference in Graphene Nanoconstrictions.

Nano letters 16 (2016) 4210-4216

P Gehring, H Sadeghi, S Sangtarash, CS Lau, J Liu, A Ardavan, JH Warner, CJ Lambert, GAD Briggs, JA Mol

We report quantum interference effects in the electrical conductance of chemical vapor deposited graphene nanoconstrictions fabricated using feedback controlled electroburning. The observed multimode Fabry-Pérot interferences can be attributed to reflections at potential steps inside the channel. Sharp antiresonance features with a Fano line shape are observed. Theoretical modeling reveals that these Fano resonances are due to localized states inside the constriction, which couple to the delocalized states that also give rise to the Fabry-Pérot interference patterns. This study provides new insight into the interplay between two fundamental forms of quantum interference in graphene nanoconstrictions.


Spin pumping through a topological insulator probed by x-ray detected ferromagnetic resonance

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS 400 (2016) 178-183

AI Figueroa, AA Baker, LJ Collins-McIntyre, T Hesjedal, G van der Laan


On the temperature dependence of spin pumping in ferromagnet-topological insulator-ferromagnet spin valves

Results in Physics 6 (2016) 293-294

AA Baker, AI Figueroa, G van der Laan, T Hesjedal


Experimental and Theoretical Electron Density Analysis of Copper Pyrazine Nitrate Quasi-Low-Dimensional Quantum Magnets.

Journal of the American Chemical Society 138 (2016) 2280-2291

LHR Dos Santos, A Lanza, AM Barton, J Brambleby, WJA Blackmore, PA Goddard, F Xiao, RC Williams, T Lancaster, FL Pratt, SJ Blundell, J Singleton, JL Manson, P Macchi

The accurate electron density distribution and magnetic properties of two metal-organic polymeric magnets, the quasi-one-dimensional (1D) Cu(pyz)(NO3)2 and the quasi-two-dimensional (2D) [Cu(pyz)2(NO3)]NO3·H2O, have been investigated by high-resolution single-crystal X-ray diffraction and density functional theory calculations on the whole periodic systems and on selected fragments. Topological analyses, based on quantum theory of atoms in molecules, enabled the characterization of possible magnetic exchange pathways and the establishment of relationships between the electron (charge and spin) densities and the exchange-coupling constants. In both compounds, the experimentally observed antiferromagnetic coupling can be quantitatively explained by the Cu-Cu superexchange pathway mediated by the pyrazine bridging ligands, via a σ-type interaction. From topological analyses of experimental charge-density data, we show for the first time that the pyrazine tilt angle does not play a role in determining the strength of the magnetic interaction. Taken in combination with molecular orbital analysis and spin density calculations, we find a synergistic relationship between spin delocalization and spin polarization mechanisms and that both determine the bulk magnetic behavior of these Cu(II)-pyz coordination polymers.


Muon-spin relaxation study of the double perovskite insulators Sr2 BOsO6 (B  =  Fe, Y, ln).

Journal of physics. Condensed matter : an Institute of Physics journal 28 (2016) 076001-

RC Williams, F Xiao, IO Thomas, SJ Clark, T Lancaster, GA Cornish, SJ Blundell, W Hayes, AK Paul, C Felser, M Jansen

We present the results of zero-field muon-spin relaxation measurements made on the double perovskite insulators Sr2 BOsO6 (B = Fe,Y, In). Spontaneous muon-spin precession indicative of quasistatic long range magnetic ordering is observed in Sr2FeOsO6 within the AF1 antiferromagnetic phase for temperatures below [Formula: see text] K. Upon cooling below T2≈67 K the oscillations cease to be resolvable owing to the coexistence of the AF1 and AF2 phases, which leads to a broader range of internal magnetic fields. Using density functional calculations we identify a candidate muon stopping site within the unit cell, which dipole field simulations show to be consistent with the proposed magnetic structure. The possibility of incommensurate magnetic ordering is discussed for temperatures below TN = 53 K and 25 K for Sr2YOsO6 and Sr2InOsO6, respectively.


Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system.

Chemical communications (Cambridge, England) 52 (2016) 12653-12656

JL Manson, JA Schlueter, KE Garrett, PA Goddard, T Lancaster, JS Möller, SJ Blundell, AJ Steele, I Franke, FL Pratt, J Singleton, J Bendix, SH Lapidus, M Uhlarz, O Ayala-Valenzuela, RD McDonald, M Gurak, C Baines

The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.


La2SrCr2O7F2: A Ruddlesden-Popper Oxyfluoride Containing Octahedrally Coordinated Cr(4+) Centers.

Inorganic chemistry 55 (2016) 3169-3174

R Zhang, G Read, F Lang, T Lancaster, SJ Blundell, MA Hayward

The low-temperature fluorination of the n = 2 Ruddlesden-Popper phase La2SrCr2O7 yields La2SrCr2O7F2 via a topochemical fluorine insertion reaction. The structure-conserving nature of the fluorination reaction means that the chromium centers of the initial oxide phase retain an octahedral coordination environment in the fluorinated product, resulting in a material containing an extended array of apex-linked Cr(4+)O6 units. Typically materials containing networks of octahedrally coordinated Cr(4+) centers can only be prepared at high pressure; thus, the preparation of La2SrCr2O7F2 demonstrates that low-temperature topochemical reactions offer an alternative synthesis route to materials of this type. Neutron diffraction, magnetization, and μ(+)SR data indicate that La2SrCr2O7F2 undergoes a transition to an antiferromagnetic state below TN ≈ 140 K. The structure-property relations of this phase and other Cr(4+) oxide phases are discussed.


Intermediate magnetization state and competing orders in Dy2Ti2O7 and Ho2Ti2O7.

Nature communications 7 (2016) 12592-

RA Borzi, FA Gómez Albarracín, HD Rosales, GL Rossini, A Steppke, D Prabhakaran, AP Mackenzie, DC Cabra, SA Grigera

Among the frustrated magnetic materials, spin-ice stands out as a particularly interesting system. Residual entropy, freezing and glassiness, Kasteleyn transitions and fractionalization of excitations in three dimensions all stem from a simple classical Hamiltonian. But is the usual spin-ice Hamiltonian a correct description of the experimental systems? Here we address this issue by measuring magnetic susceptibility in the two most studied spin-ice compounds, Dy2Ti2O7 and Ho2Ti2O7, using a vector magnet. Using these results, and guided by a theoretical analysis of possible distortions to the pyrochlore lattice, we construct an effective Hamiltonian and explore it using Monte Carlo simulations. We show how this Hamiltonian reproduces the experimental results, including the formation of a phase of intermediate polarization, and gives important information about the possible ground state of real spin-ice systems. Our work suggests an unusual situation in which distortions might contribute to the preservation rather than relief of the effects of frustration.


Selectively enhanced photocurrent generation in twisted bilayer graphene with van Hove singularity.

Nature communications 7 (2016) 10699-

J Yin, H Wang, H Peng, Z Tan, L Liao, L Lin, X Sun, AL Koh, Y Chen, H Peng, Z Liu

Graphene with ultra-high carrier mobility and ultra-short photoresponse time has shown remarkable potential in ultrafast photodetection. However, the broad and weak optical absorption (∼ 2.3%) of monolayer graphene hinders its practical application in photodetectors with high responsivity and selectivity. Here we demonstrate that twisted bilayer graphene, a stack of two graphene monolayers with an interlayer twist angle, exhibits a strong light-matter interaction and selectively enhanced photocurrent generation. Such enhancement is attributed to the emergence of unique twist-angle-dependent van Hove singularities, which are directly revealed by spatially resolved angle-resolved photoemission spectroscopy. When the energy interval between the van Hove singularities of the conduction and valance bands matches the energy of incident photons, the photocurrent generated can be significantly enhanced (up to ∼ 80 times with the integration of plasmonic structures in our devices). These results provide valuable insight for designing graphene photodetectors with enhanced sensitivity for variable wavelength.


Ordering Gold Nanoparticles with DNA Origami Nanoflowers.

ACS nano 10 (2016) 7303-7306

R Schreiber, I Santiago, A Ardavan, AJ Turberfield

Nanostructured materials, including plasmonic metamaterials made from gold and silver nanoparticles, provide access to new materials properties. The assembly of nanoparticles into extended arrays can be controlled through surface functionalization and the use of increasingly sophisticated linkers. We present a versatile way to control the bonding symmetry of gold nanoparticles by wrapping them in flower-shaped DNA origami structures. These "nanoflowers" assemble into two-dimensonal gold nanoparticle lattices with symmetries that can be controlled through auxiliary DNA linker strands. Nanoflower lattices are true composites: interactions between the gold nanoparticles are mediated entirely by DNA, and the DNA origami will fold into its designed form only in the presence of the gold nanoparticles.


The magneto-Hall difference and the planar extraordinary Hall balance

AIP ADVANCES 6 (2016) ARTN 045019

SL Zhang, T Hesjedal


Nanoscale depth-resolved polymer dynamics probed by the implantation of low energy muons

POLYMER 105 (2016) 516-525

FL Pratt, T Lancaster, PJ Baker, SJ Blundell, T Prokscha, E Morenzoni, A Suter, HE Assender

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